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PFAS can now be destroyed, not just captured

Yesterday I wrote that the carbon–fluorine bond is the strongest in organic chemistry and that nothing much breaks it. That is still true at your kitchen sink. It is no longer true everywhere — and the most interesting thing about the machines now breaking it is that they work better the more concentrated the water is.

A heavy-flanged glass and stainless pressure vessel in a treatment plant, with white crystals precipitating out of the clear fluid inside it.
A pressure vessel with solids dropping out of solution. The photograph is an illustration rather than a supercritical water reactor, but it shows the behaviour that matters: past its critical point water stops holding salts and lets them fall out, which is part of why the same fluid will hold a PFAS molecule and an oxygen molecule together long enough to break the bond between carbon and fluorine.

Yesterday I made a point about PFAS that I want to take back — carefully, and only partly.

I wrote that the carbon–fluorine bond is the strongest single bond in organic chemistry, that chemists built these compounds precisely because nothing breaks them, and that “forever chemicals” is not rhetoric but a description of a bond.

Every word of that is still accurate. But it describes the problem, not the state of the art. Because over the last few years a set of machines has arrived that does break it, and in April the EPA published a document that tells you exactly where the field stands.

That document is worth knowing about, because it is unusually honest.

The problem nobody talks about

Start with something uncomfortable about filtration, which is my own trade.

Activated carbon does not destroy PFAS. Reverse osmosis does not destroy PFAS. Ion exchange does not destroy PFAS. Every one of those technologies does the same fundamental thing: it takes PFAS out of the water and puts it somewhere else.

That somewhere else is a saturated carbon cartridge, a reverse osmosis concentrate stream, or a spent ion-exchange brine. The water leaving is cleaner. The PFAS has not gone anywhere — it has been gathered up and made portable.

For a household that is exactly what you want. The problem moves off your tap and into a cartridge you hand back. But multiply it by a country’s worth of treatment plants and you have collected an enormous quantity of a compound nobody could destroy.

Until recently there were three things you could do with it, and the EPA has now set them out formally.

What the EPA actually said in April

On 20 April 2026 the agency published its Interim Guidance on the Destruction and Disposal of PFAS, consolidating the research through September 2025. It covers three established, commercially available pathways.

Thermal treatment. Hazardous waste incineration, cement kilns, lightweight aggregate kilns. Combustion above 800°C with three to four seconds in the flame zone, and a regulatory requirement of 99.9999% destruction and removal efficiency. Air pollution control equipment is needed to capture the hydrogen fluoride that comes off.

Landfilling. Subtitle C hazardous waste cells with double composite liners, leachate collection and leak detection. The EPA is plain that this is containment, not destruction. The PFAS is still PFAS; it is behind engineering.

Underground injection. Class I wells, below 1,500 feet, isolated from drinking water. Practical mostly for liquids — reverse osmosis concentrate, ion-exchange brine — and only where the geology allows it, which in this country means the Great Plains rather than the coasts.

Burn it, bury it, or put it underground. Two of those three are storage.

The fourth category

Here is the part I find genuinely interesting, and it is where the EPA’s language rewards a close read:

“EPA partnered with industry and academia to collect data on emerging technologies for PFAS destruction, such as mechanochemical degradation, gasification and pyrolysis, and supercritical water oxidation. While the results from these studies show promise for PFAS destruction, further work using newly available methods is needed to more fully characterize the outputs of these processes.”

And then, more directly:

“In 2026, EPA is neither recommending nor discouraging the use of any emerging technology.”

Read that carelessly and it sounds like a shrug. Read it properly and it is a regulator saying: this works well enough that we are not going to stand in its way, and not yet well enough that we will put our name on it. Instead of a recommendation the agency published an evaluation framework — a way for a water utility or a base commander to judge these systems themselves.

That is the posture of a field that has moved from laboratory to field trial and is waiting on the paperwork.

What supercritical water actually is

The technology with the most real-world data behind it is supercritical water oxidation, and the physics of it is the best thing I have read all month.

Water has a critical point: 374°C and about 3,200 pounds per square inch. Push it past that and it stops being a liquid, and stops being steam, and becomes something else — a single dense phase that is neither.

In that state it behaves backwards. Ordinary water dissolves salt and refuses oil. Supercritical water dissolves oil and organic compounds freely, mixes with oxygen in any proportion, and drops salt out of solution as a solid.

So you have a fluid that will hold a PFAS molecule and an oxygen molecule in intimate contact, at a temperature where the carbon–fluorine bond finally has somewhere to go. The fluorine comes off as inorganic fluoride. The carbon leaves as carbon dioxide. The molecule is not moved. It is gone.

The field results, and why they surprised me

The best public demonstration ran at Peterson Space Force Base, treating firefighting foam waste — some of the most concentrated PFAS material that exists. The system ran at 625°C and 3,500 psi: hotter than a self-cleaning oven at full cycle, at roughly a hundred times the pressure in a car tyre.

Three runs, at three different concentrations:

  • Unconcentrated feed — 94.3% of PFAS destroyed.
  • 50% concentrated — 99.2% destroyed.
  • 79% concentrated — 99.7% destroyed, and this run met all five of the EPA’s maximum contaminant levels for regulated PFAS.

Look at the direction of that.

Every intuition says a treatment process should struggle as the contamination gets worse. This one improves. The dirtier the feed, the more completely it destroys what is in it.

There is a plain reason for it. The reaction is exothermic; PFAS destruction releases heat. A dilute feed is mostly water, and you spend your energy heating water that was not the problem. Concentrate it first and the reaction begins to sustain itself.

Which leads somewhere I did not expect when I started reading.

Filtration and destruction are the same job

If destruction works best on concentrated waste, then something has to do the concentrating.

That is precisely what a filter is for. Activated carbon takes PFAS out of thousands of gallons and holds it in a cartridge. Reverse osmosis splits a stream into clean water and a concentrate carrying everything that did not pass. Ion exchange loads a resin and releases it into a small volume of brine.

Every one of those is a concentration step. The destruction technologies are not a replacement for filtration — they are the second half of a process whose first half has existed for decades, and they get better at their end of the job the better filtration does at its own.

At Peterson the most concentrated run handled the smallest volume, 237 litres against 1,360 for the dilute run, and carried the most PFAS mass of any of them. That is the whole argument in one line: a small amount of very dirty water is a far easier thing to destroy than a large amount of slightly dirty water.

The filter makes the destruction possible. The destruction is what finally makes the filter’s output disposable.

What else is coming

Supercritical water oxidation is furthest along, but it is not alone, and the honest summary is that each of these is strong somewhere and awkward somewhere else.

  • Electrochemical oxidation. Passes current through the water and breaks the bond by direct electron transfer. In advanced pilots. The effective electrodes are boron-doped diamond, which works and is expensive, and the high potentials involved can generate chlorate and perchlorate that then need dealing with.
  • Non-thermal plasma. Better than 90% destruction of long-chain PFAS in a single pass, with field trials completed. Incomplete breakdown can leave shorter-chain PFAS behind, which is its main open question.
  • Thermal steam plasma. A core near 11,000 K, which dissociates essentially anything. Roughly 60% of the equipment footprint is gas scrubbing, and the fluorine comes out as a benign mineral product.
  • Hydrothermal alkaline treatment. 250 to 400°C under pressure, using hydroxide to attack the bond chemically rather than thermally. Needs a great deal of caustic, and the conditions are hard on equipment.
  • Sonolysis. Ultrasound, elegantly simple, completely mineralises what it treats, and consumes so much energy that it only makes sense on small concentrated streams.

Notice what nearly all of them have in common. They are best suited to concentrates. Again.

What this means at your kitchen sink

Nothing changes today, and that is not a disappointment.

None of this is household equipment. Supercritical water at 3,500 psi belongs on an industrial skid with a trained operator, not under anyone’s sink, and it will stay there.

What changes is the shape of the problem. For twenty years the honest answer about PFAS was that we could move it but not end it, and every filter in the country was writing cheques against a disposal system that did not exist. That is no longer the case. The disposal end is catching up, the EPA has published a framework for judging it, and the first field results are better than the people running them expected.

Meanwhile the household side of this was settled before the rule existed and has not moved. The EPA still names three technologies for reducing PFAS in home drinking water — granular activated carbon, ion exchange, and reverse osmosis — and certification under NSF/ANSI 53 or 58 for PFAS reduction is still the thing to look for, with those last three words still doing the work.

So the position is a good one. The thing you can control, you could already control. The thing you could not control — what happens to it afterwards — has spent five years quietly becoming solvable.

That is not a story about a chemical nobody can beat. It is a story about a bond that held out for seventy years and is now, in a few hundred litres at a time, starting to lose.

Sources

  1. US EPA — Interim Guidance on the Destruction and Disposal of PFAS and Materials Containing PFAS (20 April 2026)
  2. US EPA — Identifying Drinking Water Filters Certified to Reduce PFAS
  3. Journal of Hazardous Materials Advances — PFAS destruction using supercritical water oxidation at Peterson Space Force Base
  4. ACS ES&T Water — Field demonstration of PFAS destruction in alcohol-resistant AFFFs using supercritical water oxidation
  5. SERDP/ESTCP — PFAS destruction technology demonstrations
  6. The Chemical Engineer — Breaking down barriers: innovations in PFAS destruction
  7. 40 CFR 264.343 — Destruction and removal efficiency requirements for hazardous waste incinerators

Every figure in this article comes from the published sources listed above. This is general information, not advice about the water at any particular address.

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