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Hardness and scale

What water hardness is, and what to do about it

Tulsa runs two treatment plants and they do not deliver the same water. One is hard by the federal yardstick and one is not, and which you get depends on your address. The study everyone quotes about hard water wrecking appliances was run on water three times harder than either.

A glass shower door covered in white mineral spotting and streaks, with grey tile and a brushed nickel handle behind it.

Most people meet water hardness on a shower door. A white film that will not wipe off, spots that come back a day after the glass was cleaned, a kettle with a crust in the bottom of it. It looks like a cleaning failure. It is not. It is rock.

What it actually is, how much of it Tulsa has, and what can honestly be done about it are four separate questions, and the answers are less dramatic and more interesting than the advertising on either side suggests.

Hardness is dissolved rock, and it is measured in two units

Rain is soft. It picks up hardness on the way to you, by moving through ground that contains calcium and magnesium — limestone, chalk, dolomite — and dissolving a little of each. By the time the water reaches a treatment plant it is carrying those two metals in solution, and no amount of chlorination or filtration at the plant takes them out, because nobody is trying to.

It gets reported two ways, which is the first thing that confuses people. Milligrams per litre as calcium carbonate is the scientific unit. Grains per gallon is the plumbing-trade unit. One grain per gallon is 17.1 mg/L. Any time two sources appear to disagree wildly about your water, check whether one of them is quoting grains.

The US Geological Survey sorts the result into four bands:

SOFT MODERATELY HARD HARD VERY HARD 0–60 61–120 121–180 above 180 milligrams per litre, as calcium carbonate MOHAWK · 89 A.B. JEWELL · 140
Tulsa’s two treatment plants sit in different bands on the USGS scale. Figures from the City of Tulsa; classification from the US Geological Survey.

Tulsa has two answers, and yours depends on your address

The City of Tulsa publishes hardness per plant, and the two numbers are not close. A.B. Jewell runs 8.2 grains per gallon, or 140 parts per million. Mohawk runs 5.2 grains, or 89.

Put those on the USGS scale and they land in different categories. Jewell water is hard. Mohawk water is moderately hard — the band below. Same city, same utility, same bill, and a difference of 51 mg/L depending on which plant your street is fed from.

This is worth knowing before anyone quotes you anything, because a great deal of what gets said about Tulsa water is said about a city-wide average that does not exist. If a salesman tells you your water is hard, the reasonable question is which plant serves you, and the better one is what the number is at your own tap rather than at the plant. Hardness does not change much in the pipes, but your house may be on a blend.

It is not a health problem, and no regulator treats it as one

Worth saying plainly, because the marketing around hardness often implies otherwise: the EPA does not regulate it. There is no maximum contaminant level for hardness. It is not on the primary list, which covers things that can make you ill, and it is not on the secondary list either — the fifteen nuisance substances covering aluminium, chloride, colour, copper, corrosivity, fluoride, foaming agents, iron, manganese, odour, pH, silver, sulphate, total dissolved solids and zinc. Hardness appears in that document only as a side effect of total dissolved solids.

And the secondary standards are not enforceable anyway. The EPA describes them as “non-mandatory water quality standards” and says directly that it does not enforce them; they exist to help utilities manage the aesthetic side of what they deliver.

Calcium and magnesium are nutrients. Nobody is harmed by drinking them at these concentrations, and the water in a glass is fine. Hardness is an equipment and housekeeping question, not a safety one, and anyone selling it to you as a safety one is telling you something the federal government does not.

The study everyone quotes, and what it actually tested

There is one piece of research behind nearly every claim you will read about hard water and appliances. In 2009 the Battelle Memorial Institute ran a controlled study on water heaters, showerheads and fixtures, and the findings are genuinely striking:

Gas storage water heaters lost up to 24% of their efficiency over a simulated fifteen-year life on hard water, while the units fed softened water held their factory efficiency throughout. Tankless water heaters failed completely at 1.6 years of equivalent service, plugged solid with scale. Showerheads lost 75% of their flow in under eighteen months, and faucet strainers were close to fully blocked after nineteen equivalent days of use.

Those numbers get quoted constantly, and they are real. Two things rarely get quoted alongside them.

The first is the water. The heaters were tested at 30 grains per gallon and the tankless units at 26. Tulsa’s harder plant delivers 8.2. The study was run on water roughly three to four times harder than anything coming out of a Tulsa main, and the failures it produced are the failures of that water, not of yours.

The second is who paid for it. The study was commissioned by the Water Quality Research Foundation, which is the research arm of the Water Quality Association — the trade body for the industry that sells water softeners. That does not make the findings wrong. Battelle is a serious laboratory and the work was done properly. It does mean the questions asked were the questions a softener industry wanted answered, and it is the kind of thing a reader deserves to be told rather than left to discover.

What survives both caveats is the mechanism, and the mechanism is the part that matters. Scale forms when hard water is heated, because calcium carbonate becomes less soluble as temperature rises — which is why the crust turns up in the kettle, the heater and the dishwasher rather than in the cold line. That happens at 8 grains exactly as it happens at 30. It happens more slowly, in proportion to how much calcium is going past. Battelle’s own rate figure is about four percent of efficiency lost per five grains of hardness; carry that down to Tulsa’s 8.2 and you get something in the region of six or seven percent across fifteen years. That is our arithmetic on their number, not their finding, and it is worth about what any extrapolation is worth. But it is the right order of magnitude, and it is not nothing on a water heater you expected to run for fifteen years.

Two ways to deal with it, and they are not the same thing

This is where most of the confusion lives, because both approaches get sold under the word “treatment” and they do completely different jobs.

REMOVAL · ION EXCHANGE SEQUESTRATION · POLYPHOSPHATE RESIN TO DRAIN salt · drain · power calcium gone P 2–4 ppm calcium stays in the water, wrapped so it cannot nucleate on the pipe wall no salt · no drain · no power
Removal takes the calcium out of the house. Sequestration leaves it in the water and stops it sticking. Only one of them softens.

Removal is ion exchange, which is what a water softener does. Water passes through a bed of resin that holds sodium; the resin swaps its sodium for the calcium and magnesium going past, and the water that comes out the other side genuinely has the hardness taken out of it. That is the only approach that ends the shower-door problem, because the shower door is calcium drying on glass and there is no calcium left to dry.

It costs something to do that. A softener needs salt, a drain connection, electricity, and a periodic regeneration cycle that flushes the captured hardness away and refills the resin with sodium. It puts that sodium into your water in place of the calcium — a small amount, proportional to how hard the water was, and worth knowing about if anyone in the house is counting it. And a proportion of municipal water goes down the drain every time it regenerates.

Sequestration is a different idea entirely. A food-grade polyphosphate is dosed into the water, and it wraps the calcium and magnesium in soluble complexes so they stay dissolved and travel on through the house rather than coming out of solution on a heating element. Nothing is removed. The hardness leaves with the water.

What makes it practical is an effect worth understanding, because it sounds too good on the face of it. Fully binding 200 ppm of hardness would stoichiometrically take around 500 ppm of sodium hexametaphosphate — an absurd dose. In practice two to four parts per million does the job, because the polyphosphate does not need to wrap every ion; it only needs to interfere with the first crystals as they try to form. Scale needs a seed to grow on, and a tiny dose is enough to stop the seed. The trade calls it threshold treatment, and it is why a cartridge the size of a forearm can protect a whole house.

The honest limits: it does not soften. Your water still has every bit of its hardness in it, soap will behave the way it always has, and the glass door will still need a squeegee. And polyphosphate hydrolyses faster as water gets hotter, so it is a protection that works best before and up to the heater rather than deep inside a tank that runs very hot.

What it does protect is the part you cannot see and cannot clean — the inside of the pipework, the heating element, the valves in a dishwasher and a washing machine, the narrow passages where a tankless heater actually fails. It does that with no salt to carry, no drain to plumb, no power, no regeneration cycle, no water sent down the drain, and no sodium added to what you drink. On line pressure alone, it keeps working through a power cut.

So what should you actually do

Find out which plant serves you, because that is a 51 mg/L question and it is free to answer. Then measure at your own tap rather than reasoning from the plant figure.

If the number comes back in the very hard band — which happens on private wells around here far more than on city water — removal is the honest answer and sequestration will not do what you want. If it comes back where Tulsa’s city water sits, the question is narrower and more useful: you are not trying to rescue a system from 30-grain water, you are trying to keep a moderate, steady calcium load from quietly costing you efficiency on a heater over fifteen years. That is a protection problem rather than a rescue, and it is proportionate to treat it as one.

Either way, the spots on the glass are cosmetic and reversible. Scale on a heating element is neither. If you only deal with one of the two, deal with the one you cannot see.

This article is general information about water chemistry and public data. It is not plumbing advice. Hardness figures are the City of Tulsa’s own published values by treatment plant and can change; the classification bands are the US Geological Survey’s. The fifteen-year efficiency figure derived from the Battelle rate is our arithmetic applied to Tulsa’s hardness, not a finding of that study.

Sources

  1. City of Tulsa — FAQs about water, including hardness by treatment plant
  2. USGS — Hardness of water, classification table
  3. EPA — Secondary drinking water standards: guidance for nuisance chemicals
  4. Battelle Memorial Institute — Study findings for the Water Quality Research Foundation
  5. Phosphate Forum of the Americas — The use of phosphates for potable water treatment

Every figure in this article comes from the published sources listed above. This is general information, not advice about the water at any particular address.

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